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@@ -151,8 +151,9 @@ Extended BZ (n-th band within n-th BZ):
@@ -321,7 +322,7 @@ Here $E'_G\approx 0.9eV$ and $E_G\approx 0.8 eV$. The two steps visible steps ar
Photons carry very little momentum and a very high energy since $E = c \hbar k$ and $c$ is large. Therefore to excite electrons at $E_G$, despite a lower photon energy is sufficient, there is not enough momentum. Then an extra phonon is required. Phonons may have a very large momentum at room temperature, and a very low energy since atomic mass is much higher than electron mass.