@@ -281,7 +281,7 @@ Suppose we have a crystal with lattice vectors $\mathbf{a}_ 1$, $\mathbf{a}_ 2$,
...
@@ -281,7 +281,7 @@ Suppose we have a crystal with lattice vectors $\mathbf{a}_ 1$, $\mathbf{a}_ 2$,
1. What can be said about the symmetry of the Hamiltonian $\hat{H}$ of this crystal?
1. What can be said about the symmetry of the Hamiltonian $\hat{H}$ of this crystal?
Now define the translation operator $\hat{T}_{\alpha,\beta,\gamma}$ so that
To describe the translation through the crystal in terms of the lattice vectors, we define the translation operator $\hat{T}_{\alpha,\beta,\gamma}$ in such a way that
@@ -296,18 +296,20 @@ where $\mathbf{\hat{p}} =-i\hbar\nabla$.
...
@@ -296,18 +296,20 @@ where $\mathbf{\hat{p}} =-i\hbar\nabla$.
5. What is $u_{n,\mathbf{k}}(\mathbf{r})$ in case of free electrons? Is your answer consistent with the equation above?
5. What is $u_{n,\mathbf{k}}(\mathbf{r})$ in case of free electrons? Is your answer consistent with the equation above?
### Exercise 2: the central equation in 1D
### Exercise 2: the central equation in 1D
Let's consider a 1D crystal with a period $a$. Let $k_0$ be any wave number of an electron in the first Brillouin zone.
Let's consider a 1D crystal with a periodicity of $a$.
1. What $k_n$ are equivalent to $k_0$ in this crystal?
Let $k_0$ be any wave number of an electron in the first Brillouin zone.
1. Which $k_n$ are equivalent to $k_0$ in this crystal?
2. First, we assume that the electrons with these $k_n$ are free. In that case, what are the wavefunctions $\phi_n(x)$ and energies $E_n$ of these electrons?
2. First, we assume that the electrons with these $k_n$ are free. In that case, what are the wavefunctions $\phi_n(x)$ and energies $E_n$ of these electrons?
3. Make a sketch of the dispersion relation using a repeated Brillouin zone representation. Indicate some $k_n$ and $E_n$ as well as the first Brillouin zone in your sketch.
3. Make a sketch of the dispersion relation using a repeated Brillouin zone representation. Indicate some $k_n$ and $E_n$ as well as the first Brillouin zone in your sketch.
We will now introduce a weak periodic potential $V(x) = V(x+na)$ in our system. This causes coupling between eigenstates $\left| \phi_n\right>$ in the free electron case. In order to find the right eigenstates of the system with that potential, we need an 'LCAO-like' trial eigenstate given by
We will now introduce a weak periodic potential $V(x) = V(x+na)$ to the system, which causes coupling between eigenstates $\left| \phi_n\right>$ of the free electrons.
In order to find the right eigenstates of the system with that potential, we use an 'LCAO-like' trial eigenstate