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1st major update to lecture note 4

Merged Maciej Topyla requested to merge maciejedits into master
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@@ -10,9 +10,9 @@ The lecture on vector spaces in quantum mechanics consists of the following part
- [4.2. Inner product of state vectors](#42-inner-product-of-state-vectors)
- [4.3. Matrix representation of ket and bra vectors](#43-matrix-representation-ket-bra-vectors)
- [4.3. Matrix representation of ket and bra vectors](#43-matrix-representation-ket-and-bra-vectors)
- [4.4. A two-dimensional Hilbert space](#44-two-dimensional-hilbert-space)
- [4.4. A two-dimensional Hilbert space](#44-a-two-dimensional-hilbert-space)
and at the end of the lecture there is a set of exercises
@@ -28,7 +28,7 @@ The contents of this lecture are summarised in the following **videos**:
- [3. Finding expansion coefficients for Dirac notation](https://www.dropbox.com/s/k9plspkonnk3nc0/linear_algebra-07.mov?dl=0)
**Total lenght of the videos: ~14 minutes**
**Total length of the videos: ~14 minutes**
---
@@ -45,7 +45,7 @@ This vector space is known as the *state space* of the system.
!!! info "Ket"
A physical state of a quantum system is represented by a symbol $$|~~\rangle$$ known as a **ket**.
This notation is known as the *Dirac notation*, and it is very prominent in the description of quantum mechanics.
Note that a *ket* is also refered to as a state vector, *ket* vector, or just a state.
Note that a *ket* is also referred to as a state vector, *ket* vector, or just a state.
### Hilbert space
@@ -72,7 +72,7 @@ The set of all possible state vectors describing a given physical system forms a
$$\sum_{i=1}^n c_i |{\psi_i}\rangle=0\;\text{then}\; c_i=0\;\text{for all}\; i$$
!!! info "Dimensionality"
The minimum number of vectors needed to form a complete set of basis states is known as the *dimensionality* of the state space. In quantum mechanis you will encounter systems whose Hilbert spaces have very different dimensionality, from the spin-1/2 particle (a $n=2$ vector space) to the free particle (whose state vectors live in an infinite vector space).
The minimum number of vectors needed to form a complete set of basis states is known as the *dimensionality* of the state space. In quantum mechanics you will encounter systems whose Hilbert spaces have very different dimensionality, from the spin-1/2 particle (a $n=2$ vector space) to the free particle (whose state vectors live in an infinite vector space).
### Bra vectors
@@ -95,7 +95,7 @@ between them, $\langle{\psi}|{\phi}\rangle$, as follows.
The inner product in quantum mechanics is the analog of the usual scalar product that one encounters in vector spaces, and which we reviewed in the previous lecture. As in usual vector spaces, the inner product of two state vectors is a *scalar* and in this case a complex number in general.
!!! tip "Meaning of the inner product in quantum mechanics"
!!! tip "Interpretation of the inner product in quantum mechanics"
1. The value of the inner product $\langle{\psi}|{\phi}\rangle$ indicates the **probability amplitude** (not the probability) of measuring a system, which characterised by the state $|{\phi}\rangle$, to be in the state $|{\psi}\rangle$.
2. This inner product can also be understood as measuring the **overlap** between the state vectors $|{\psi}\rangle$ and $|{\phi}\rangle$.
3. Then the **probability of observing the system to be in the state $|\psi\rangle$** given that it is in the state $|\phi\rangle$ will be given by $$|\langle \psi | \phi \rangle|^2 \, .$$ Since the latter quantity is a probability, we know that it should satisfy the condition that
@@ -135,12 +135,9 @@ We can also express the basis vectors in this manner. Given that the basis vecto
the basis state $|\phi_i\rangle$ will have as component in the $j$ direction
$$ (\phi_i)_j=\langle \phi_j|\phi_i\rangle=\delta_{ji} \, ,$$
and thus the vector column expression of the basis vectors will be very simple
$$
|\phi_1\rangle= \begin{pmatrix} 1\\0\\0 \\\vdots\end{pmatrix} \;, \quad
|\phi_2\rangle= \begin{pmatrix} 0\\1\\0 \\\vdots\end{pmatrix} \;, \ldots
$$
$$ |\phi_1\rangle= \begin{pmatrix} 1\\0\\0 \\\vdots\end{pmatrix} \;, \quad |\phi_2\rangle= \begin{pmatrix} 0\\1\\0 \\\vdots\end{pmatrix} \;, \ldots $$
!!! example "Evaluating an inner product"
!!! note "Evaluating the inner product"
Let us show how we can use the matrix representation to evaluate the inner product (bracket) between two state vectors when expanded in terms of their components in the same basis:
$$ |\psi\rangle=\sum_{i=1}^n \psi_i |\phi_i\rangle \,, \qquad |\chi\rangle=\sum_{i=1}^n \chi_i |\phi_i\rangle\, .$$
First of all, we note that we can write the above expansions in the following way
@@ -168,7 +165,7 @@ $$
$$\langle \chi|\psi\rangle=\begin{pmatrix} \chi^*_1 , \chi^*_2 &,\ldots \end{pmatrix}\begin{pmatrix} \psi_1 \\ \psi_2 \\ \vdots \end{pmatrix} \, .$$ Therefore, we can present bra vector $\langle \chi|$ as row vectors and ket vectors as column vector.
The row vector can thus be treated as the *complex conjugate* of the corresponding column vector.
## A two-dimensional Hilbert space
## 4.4. A two-dimensional Hilbert space
As a practical example to illustrate the basic ideas of vector spaces applied to quantum physics presented above, we will consider a quantum system which is fundamental for quantum mechanics and its applications. This system corresponds to the possible states that the intrinsic angular momentum of an electron, known as *spin*, can occupy. As you will see in following courses, the Hilbert space for the electron spin has dimension $n=2$, meaning that we can found an electron *pointing* either in the up direction, denoted by $|+\rangle$, or the down direction, denoted by $|-\rangle$.
@@ -207,11 +204,13 @@ $$
$$
The values of the coefficients $c_+$ and $c_-$ for these examples above are, respectively,
$$
(c_+,c_) = (3,-2i) \, ,\qquad
(c_+,c_-) = (3,-2i) \, ,\qquad
(c_+,c_-) = (i,-4) \, ,\qquad
(c_+,c_-) = (2,5) \, .\qquad
$$
Note however that many other bases are possible, and that the physics of a quantum system do not depend on the basis that we choose.
!!! warning ""
Note however that many other bases are possible, and that the physics of a quantum system do not depend on the basis that we choose.
The bra vectors associated to these ket vectors will be given by
$$ |{\Psi}\rangle= \left( \begin{array}{c}3 \\ -2i \end{array} \right) \, , \qquad
\langle{\Psi}|=\left( 3, 2i \right) \, ,$$
@@ -222,29 +221,30 @@ $$|{\Psi}\rangle= \left( \begin{array}{c}2 \\ 5 \end{array} \right) \, , \qquad
Note however that the above vectors are not normalised (the inner product with themselves is different from unity), and thus
cannot represent physical states. We show below an explicit example of a normalised state vector belonging to this Hilbert space.
We also know how we can evaluate the inner product between any two state vectors belonging to this Hilbert space. If we have two state vectors given by
$$
|\psi\rangle = \frac{1}{\sqrt{2}} \left( \begin{array}{c}1 \\ -i \end{array} \right) \, \quad
|\phi \rangle = \left( \begin{array}{c}0 \\1 \end{array} \right)
$$
then their inner product is
$$
\langle \psi | \phi \rangle =
\frac{1}{\sqrt{2}} \left( 1 , i \right) \left( \begin{array}{c}0 \\1 \end{array} \right) =
\frac{i}{\sqrt{2}}
$$
and the associated probability will be given by
$$
|\langle \psi|\phi\rangle|^2 = \frac{1}{2}
$$
meaning that if I measure the state $| \phi \rangle $, I will have a 50% probability
of finding it in the state $| \psi \rangle$. Recall that probabilities must always be smaller than 1 to make physical sense. Note also that I am using normalised vectors, you can check yourselves that
$$
\langle \psi |\psi \rangle = \langle \phi | \phi\rangle = 1 \, ,
$$
as required to ensure the probabilistic description of the state vector.
!!! done "Example: Evaluating the inner product"
We also know how we can evaluate the inner product between any two state vectors belonging to this Hilbert space. If we have two state vectors given by
$$
|\psi\rangle = \frac{1}{\sqrt{2}} \left( \begin{array}{c}1 \\ -i \end{array} \right) \, \quad
|\phi \rangle = \left( \begin{array}{c}0 \\1 \end{array} \right)
$$
then their inner product is
$$
\langle \psi | \phi \rangle =
\frac{1}{\sqrt{2}} \left( 1 , i \right) \left( \begin{array}{c}0 \\1 \end{array} \right) =
\frac{i}{\sqrt{2}}
$$
and the associated probability will be given by
$$
|\langle \psi|\phi\rangle|^2 = \frac{1}{2}
$$
meaning that if I measure the state $| \phi \rangle $, I will have a 50% probability
of finding it in the state $| \psi \rangle$. Recall that probabilities must always be smaller than 1 to make physical sense. Note also that I am using normalised vectors, you can check yourselves that
$$
\langle \psi |\psi \rangle = \langle \phi | \phi\rangle = 1 \, ,
$$
as required to ensure the probabilistic description of the state vector.
## Problems
## 4.5. Problems
**1)** [:grinning:] *The inner product*
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