Skip to content
Snippets Groups Projects
Commit bfa47c42 authored by Anton Akhmerov's avatar Anton Akhmerov
Browse files

fix remaining list formatting

parent 2f5385e2
No related branches found
No related tags found
No related merge requests found
......@@ -32,11 +32,6 @@
* Week 8: Magnetism
(based on chapters 19-20)
# Practice exams
## Exams from years 16-17
[Exams archive](https://solidstate.quantumtinkerer.tudelft.nl/exams_2016_2017.zip), [solutions minitests 2017 archive](https://solidstate.quantumtinkerer.tudelft.nl/solutions_2017_minitests.zip) *(caution, those solutions are not always correct)*, [solutions final](https://solidstate.quantumtinkerer.tudelft.nl/final_2017/).
## Test results
### Minitest 1
......@@ -47,6 +42,12 @@
[Results report](https://solidstate.quantumtinkerer.tudelft.nl/summary_report_midterm.html), [solution](https://solidstate.quantumtinkerer.tudelft.nl/solutions_midterm.pdf)
# Practice exams
## Exams from years 16-17
[Exams archive](https://solidstate.quantumtinkerer.tudelft.nl/exams_2016_2017.zip), [solutions minitests 2017 archive](https://solidstate.quantumtinkerer.tudelft.nl/solutions_2017_minitests.zip) *(caution, those solutions are not always correct)*, [solutions final](https://solidstate.quantumtinkerer.tudelft.nl/final_2017/).
## Course book
The Oxford Solid State Basics by Steven H. Simon
......
......@@ -3,9 +3,12 @@
_Based on chapter 2 of the book_
In this lecture we will:
- discuss specific heat of a solid based on atomic vibrations (_phonons_)
- disregard periodic lattice $\rightarrow$ consider homogeneous medium
- _(chapter 9: discuss phonons in terms of atomic masses and springs)_
- discuss the Einstein model
- discuss the Debye model
- introduce reciprocal space, periodic boundary conditions and _density of states_
......
......@@ -32,6 +32,7 @@ $$
$\sigma$ is the conductivity, which is the inverse of resistivity: $\rho=\frac{1}{\sigma}$. If we now take $j=\frac{I}{A}$ and $E=\frac{V}{l}$, we retrieve Ohm's Law: $\frac{I}{A}=\frac{V}{\rho l}$.
Scattering is caused by collisions with:
- Phonons: $\tau_{\rm ph}(T)$ ($\tau_{\rm ph}\rightarrow\infty$ as $T\rightarrow 0$)
- Impurities/vacancies: $\tau_0$
......@@ -90,6 +91,7 @@ $$
![](figures/free_electron.svg)
Comparable to phonons, but: electrons are _fermions_.
- Only 2 (due to spin) allowed per $k$-value
- Fill up from the lowest energy until you run out of electrons
......@@ -118,6 +120,7 @@ $$
![](figures/sqrt.svg)
Similarly,
- For 1D: $g(\varepsilon) = \frac{2 V}{\pi} \frac{ {\rm d}k}{ {\rm d}\varepsilon} \propto 1/\sqrt{\varepsilon}$
- For 2D: $g(\varepsilon) = \frac{k V}{\pi} \frac{ {\rm d}k}{ {\rm d}\varepsilon} \propto \text{constant}$
......@@ -175,6 +178,7 @@ $$
$T_{\rm F}=\frac{\varepsilon_{\rm F}}{k_{\rm B}}$ is the _Fermi temperature_.
How does $C_{V,e}$ relate to the phonon contribution $C_{V,p}$?
- At room temperature, $C_{V,p}=3Nk_{\rm B}\gg C_{V,e}$
- Near $T=0$, $C_{V,p}\propto T^3$ and $C_{V,e}\propto T$ $\rightarrow$ competition.
......
......@@ -53,6 +53,7 @@ Single electron states have 4 quantum numbers: $|n, l, l_z, \sigma\rangle$
![](figures/single_atom.svg)
Quantum numbers:
* $n=1,2,\ldots$ is the azimuthal (principal) quantum number
* $l=0, 1, \ldots, n-1$ is the angular momentum (also known as $s, p, d, f$ orbitals)
* $l_z=-l, -l+1\ldots, l$ is the $z$-component of angular momentum
......@@ -61,7 +62,6 @@ Quantum numbers:
It turns out that electrons in all atoms occupy these orbitals, only the energies are very different.
* Aufbau principle: *first fill a complete shell (all electrons with the same $n, l$) before going to the next one*
* Madelung's rule: *first occupy the shells with the lowest $l+n$, and of those with equal $l+n$ those with smaller $n$*
Therefore shell-filling order is 1s, 2s, 2p, 3s, 3p, 4s, 4d, ...
......
......@@ -11,7 +11,9 @@ In this lecture we will:
- consider diffraction experiments on crystals
### Crystal classification
- **_Lattice_**
- periodic pattern of *lattice points*, which all have an identical view
- lattice points are not necessarily the same as atom positions
- there can be multiple atoms per lattice point
......@@ -19,34 +21,43 @@ In this lecture we will:
- multiple lattices with different point densities possible
- **_Lattice vectors_**
- from lattice point to lattice point
- $N$ vectors for $N$ dimensions
- multiple combinations possible
- not all combinations provide full coverage
- **_Unit cell_**
- spanned by lattice vectors
- has 4 corners in 2D, 8 corners in 3D
- check if copying unit cell along lattice vectors gives full lattice
- **_Primitive unit cell_**
- smallest possible $\rightarrow$ no identical points skipped
- not always most practical choice
- **_Basis_**
- only now we care about the contents (i.e. atoms)
- gives element and position of atoms
- properly count partial atoms $\rightarrow$ choose which belongs to unit cell
- positions in terms of lattice vectors, *not* Cartesian coordinates!
### Example: graphite
![](figures/graphite_mod.svg)
1. Choose origin (can be atom, not necessary)
2. Find other lattice points that are identical
3. Choose lattice vectors, either primitive (red) or not primitive (blue)
- lengths of lattice vectors and angle(s) between them fully define the crystal lattice
- for graphite: $|{\bf a}_1|=|{\bf a}_2|$ = 0.246 nm = 2.46 Å, $\gamma$ = 60$^{\circ}$
4. Specify basis
- using ${\bf a}_1$ and ${\bf a}_2$: C$(0,0)$, C$\left(\frac{2}{3},\frac{2}{3}\right)$
- using ${\bf a}_1$ and ${\bf a}_{2}'$: C$(0,0)$, C$\left(0,\frac{1}{3}\right)$, C$\left(\frac{1}{2},\frac{1}{2}\right)$, C$\left(\frac{1}{2},\frac{5}{6}\right)$
......@@ -80,6 +91,7 @@ Compare this to _body centered cubic_ (bcc), which consists of a cube with atoms
Question: is 74% the largest possible filling factor? $\rightarrow$ Kepler conjecture (1571 – 1630). Positive proof by Hales _et al._ in 2015!
Crystal structures that are related to fcc:
1. ionic crystals (Fig. 1.13), e.g. NaCl
2. zincblende (Fig. 1.15), e.g. diamond
......@@ -237,7 +249,6 @@ $$
The structure factor can cause destructive interference due to the contents of the unit cell, even though the Laue condition is met. Examples:
- Simplest case: 1 atom at each lattice point, ${\bf r}_1=(0,0,0)\rightarrow S=f_1$. In this case each reciprocal lattice point gives one interference peak, none of which is cancelled.
- Example 2: conventional cell of the fcc lattice.
![](figures/fcc_mod.svg)
......
......@@ -10,6 +10,7 @@ In this lecture we:
* Formulate a general way of computing the electron band structure, the **Bloch theorem**.
* Derive the electron band structure when the interaction with the lattice is weak using the **Nearly free electron model**. This model:
- Helps to understand the relation between tight-binding and free electron models
- Describes the properties of metals.
......@@ -20,9 +21,7 @@ All the different limits can be put onto a single scale as a function of the str
## Bloch theorem
> All Hamiltonian eigenstates in a crystal have the form
> $$ \psi_n(\mathbf{r}) = u_n(\mathbf{r})e^{i\mathbf{kr}} $$
> with $u_n(\mathbf{r})$ having the same periodicity as the lattice potential $V(\mathbf{r})$, and index $n$ labeling electron bands with energies $E_n(\mathbf{k})$.
In other words: any electron wave function in a crystal is a product of a periodic part that describes electron motion within a unit cell and a plane wave.
......@@ -66,20 +65,21 @@ $$H\begin{pmatrix}\alpha \\ \beta \end{pmatrix} =
$$
Here we used $\delta p = \hbar \delta k$, and we expanded the quadratic function into a linear plus a small correction.
**Question: can you calculate** $E_0$ **and the velocity** $v$**?**
**Question: can you calculate $E_0$ and the velocity $v$?**
Without $V(x)$ the two wave functions $\psi_+$ and $\psi_-$ are independent since they have a different momentum. When $V(x)$ is present, it may couple these two states.
So in presence of $V(x)$ the Hamiltonian becomes
$$H\begin{pmatrix}\alpha \\ \beta \end{pmatrix} =
$$
H\begin{pmatrix}\alpha \\ \beta \end{pmatrix} =
\begin{pmatrix} E_0 + v \hbar \delta k & W \\ W^* & E_0 - v \hbar \delta k\end{pmatrix}
\begin{pmatrix}\alpha \\ \beta \end{pmatrix},
$$
Here the coupling strength $W = \langle \psi_+ | V(x) | \psi_- \rangle$ is the matrix element of the potential between two states. *(This where we need to apply the perturbation theory, and this is very similar to the LCAO Hamiltonian)*.
**Question: how does our solution satisfy the Bloch theorem? What is** $u(x)$ **in this case?**
**Question: how does our solution satisfy the Bloch theorem? What is $u(x)$ in this case?**
#### Dispersion relation near the avoided level crossing
......
# Semiconductor physics
## Review of band structure properties
* Group velocity $v=\hbar^{-1}\partial E(k)/\partial k$
* Effective mass $m_{eff} = \hbar^2\left(d^2 E(k)/dk^2\right)^{-1}$
* Density of states $g(E) = \sum_{\textrm{FS}}dk \times (dn/dk) \times (dk/dE)$ the amount of states per infinitesimal interval of energy at each energy.
......@@ -113,6 +114,7 @@ $$ E = {p^2}/{2m_h}$$
$$ g(E) = (2m_h)^{3/2}\sqrt{E_h}/2\pi^2\hbar^3$$
**The key algorithm of describing the state of a semiconductor:**
1. Write down the density of states, assuming a certain position of the Fermi level
2. Calculate the total amount of electrons and holes, equate the difference to the total amount of electrons $-$ holes available.
3. Use physics intuition to simplify the equations (this is important!)
......@@ -243,4 +245,4 @@ Charge balance determins the number of electrons and holes as well as the positi
If dopant concentrations are low, then $n_e = n_h = n_i \equiv \sqrt{N_C N_V}e^{-E_G/2kT}$.
If dopant concentrations are high, then in $n$-doped semiconductor $n_e = N_D - N_A$ and $n_h = n_i^2/n_e$ (or vice versa).
\ No newline at end of file
If dopant concentrations are high, then in $n$-doped semiconductor $n_e = N_D - N_A$ and $n_h = n_i^2/n_e$ (or vice versa).
0% Loading or .
You are about to add 0 people to the discussion. Proceed with caution.
Finish editing this message first!
Please register or to comment