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Commit 06d224dd authored by Anton Akhmerov's avatar Anton Akhmerov
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learning goals week 3

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......@@ -14,6 +14,14 @@ pi = np.pi
_(based on chapters 5–8 of the book)_
Exercises 5.2, 6.2, 6.3, 6.4, 6.5
!!! summary "Learning goals"
After this lecture you will be able to:
- Describe the shell-filling model of atoms
- Derive the LCAO model
- Obtain the spectrum of the LCAO model of several orbitals
## Looking back
So far we have:
......@@ -133,6 +141,16 @@ An occupied $\psi_-$ increases the molecule energy as the atoms move closer ⇒
Therefore if each atom has a single electron in the outermost shell, these atoms attract, if there are 0 or 2 electrons, the net electron force cancels (but electrostatic repulsion remains).
*[LCAO]: Linear Combination of Atomic Orbitals
!!! summary "Learning goals"
After this lecture you will be able to:
- Explain the origins of interatomic forces
- Compute vibrational spectra of small molecules in 1D
- Write down Hamiltonians and equations of motion of bulk materials (but not yet solve them)
## Adding repulsion
If bringing two atoms closer would keep increasing energy, any covalent bond would collapse; eventually the two atoms must start repelling (at least when the nuclei get close, but really already much earlier).
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