We then substitute the Laue condition back for $\mathbf{k'}$:
We then substitute the Laue condition $\mathbf{k'} = \mathbf{k}+\mathbf{G}$:
$$
\begin{align}
...
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@@ -589,30 +589,29 @@ Note, $\phi$ is the angle between the vector $\mathbf{k}$ and $\mathbf{G}$, whic
We are nearly there, but we are left with finding out the relation between $\phi$ and $\theta$.
Last lecture we discussed the concept of Miller planes.
These were planes designated by Miller indices $(h,k,l)$ which intersect the lattice vectors at $\mathbf{a}_1 / h$, $\mathbf{a}_22 / k$ and $\mathbf{a}_3 / l$.
It turns out that these miller planes are normal the reciprocal lattice vector $\mathbf{G} = h \mathbf{b}_1 + k \mathbf{b}_2 + l \mathbf{b}_3$ and that the distance between subsequent Miller planes is given by $d_{hkl} = \frac{2 \pi}{\lvert \mathbf{G} \rvert}$ (you will derive this in [exercise](https://solidstate.quantumtinkerer.tudelft.nl/10_xray/#exercise-2-miller-planes-and-reciprocal-lattice-vectors)).
These are planes designated by Miller indices $(h,k,l)$ which intersect the lattice vectors at $\mathbf{a}_1 / h$, $\mathbf{a}_22 / k$ and $\mathbf{a}_3 / l$.
It turns out that these miller planes are normal the reciprocal lattice vector $\mathbf{G} = h \mathbf{b}_1 + k \mathbf{b}_2 + l \mathbf{b}_3$ and that the distance between subsequent Miller planes is given by $d_{hkl} = \frac{2 \pi}{\lvert \mathbf{G} \rvert}$ (you will derive this in [today's exercise](https://solidstate.quantumtinkerer.tudelft.nl/10_xray/#exercise-2-miller-planes-and-reciprocal-lattice-vectors)).
We substitute the expression of $\lvert \mathbf{G} \rvert$ into the equation of the distance:
We know that $\lvert \mathbf{k} \rvert$ is related to the wavelength by $\lvert \mathbf{k} \rvert = \pi/\lambda$.
We know that $\lvert \mathbf{k} \rvert$ is related to the wavelength by $\lvert \mathbf{k} \rvert = 2\pi/\lambda$.
Therefore, we can write the equation above as
$$
2 d_{hkl} \cos (\phi) = \lambda.
$$
We substitute $\phi = \theta - \pi/2$.
Lastly, we express the equation in terms of the deflection angle through the relation $\phi = \theta - \pi/2$.
With this, one can finally derive **Bragg's Law**:
$$
\lambda = 2 d_{hkl} \sin(\theta)
$$
This equation allows us to obtain the distance $d_{hkl}$ from an experiment.
Thus we can sue Bragg's Law in a diffraction powder diffraction experiment to obtain the distances between atoms in a crystal structre!
Bragg's law allows us to obtain atomic distances in the crystal $d_{hkl}$ through powder diffraction experiments!
## Summary
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@@ -631,7 +630,7 @@ Thus the band structure can be fully described by considering the 1st Brillouin
1. Why is the amplitude of a scattered wave zero if $\mathbf{k'}-\mathbf{k} \neq \mathbf{G}$?
2. Calculate the structure factor of the triangular lattice using the reciprocal lattice vectors found in the lecture.
Do any intensity peaks dissapear?
3. Calculate $\mathbf{a}_1 \cdot \mathbf{b}_1$ and $\mathbf{a}_2 \cdot \mathbf{b}_1$ using the definitions of the reciprocal lattice vectors given in the lecture. Is this what was expected?
3. Calculate $\mathbf{a}_1 \cdot \mathbf{b}_1$ and $\mathbf{a}_2 \cdot \mathbf{b}_1$ using the definitions of the reciprocal lattice vectors given in the lecture. Is the result what you expected?
### Exercise 1: Equivalence of direct and reciprocal lattice
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@@ -644,9 +643,9 @@ The volume of a primitive cell of a lattice with lattice vectors $\mathbf{a}_1,
3. Write down the primitive lattice vectors of the [BCC lattice](https://solidstate.quantumtinkerer.tudelft.nl/test_builds/lecture_9/9_crystal_structure/#body-centered-cubic-lattice) and calculate its reciprocal lattice vector.
Which type of lattice is the reciprocal lattice of the real-space BCC lattice?
4. Determine the shape of the 1st Brillouin zone of its reciprocal lattice.
3. Write down the primitive lattice vectors of the [BCC lattice](https://solidstate.quantumtinkerer.tudelft.nl/test_builds/lecture_9/9_crystal_structure/#body-centered-cubic-lattice) and calculate its reciprocal lattice vectors.
Which type of lattice is the reciprocal lattice of a BCC crystal?
4. Determine the shape of the 1st Brillouin zone.
### Exercise 2: Miller planes and reciprocal lattice vectors