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Verified Commit af5c176b authored by Anton Akhmerov's avatar Anton Akhmerov
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typo fixes

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1 merge request!77Solutions to lecture 5: LCAO model
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......@@ -7,22 +7,24 @@
2. The atomic number of Tungsten is 74:
$$
1s^22s^22p^63s^23p^64s^23d^{10}4p^65s^24d^{10}5p^66s^24f^{14}5d^4
1s^22s^22p^63s^23p^64s^23d^{10}4p^65s^24d^{10}5p^66s^24f^{14}5d^4
$$
3.
$$
Cu &= [Ar]4s^23d^9
Pd &= [Kr]5s^24d^8
Ag &= [Kr]5s^24d^9
Au &= [Xe]6s^24f^145d^9
\begin{align}
\textrm{Cu} &= [\textrm{Ar}]4s^23d^9
\textrm{Pd} &= [\textrm{Kr}]5s^24d^8
\textrm{Ag} &= [\textrm{Kr}]5s^24d^9
\textrm{Au} &= [\textrm{Xe}]6s^24f^145d^9
\end{align}
$$
### Question 2
1.
1.
$$
\psi(x) =
\psi(x) =
\begin{cases}
&\sqrt{\kappa}e^{\kappa(x-x_1)}, x<x_1\\
&\sqrt{\kappa}e^{-\kappa(x-x_1)}, x>x_1
......@@ -31,9 +33,9 @@ $$
Where $\kappa = \sqrt{\frac{-2mE}{\hbar^2}} = \frac{mV_0}{\hbar^2}$.
The energy is given by $\epsilon1 = \epsilon2 = -\frac{mV_0}{\hbar^2}$
The energy is given by $\epsilon_1 = \epsilon_2 = -\frac{mV_0}{\hbar^2}$
The wavefunction of a single delta peak is given by
The wave function of a single delta peak is given by
$$
\psi_1(x) = \frac{\sqrt{mV_0}}{\hbar}e^{-\frac{mV_0}{\hbar^2}|x-x_1|}
......@@ -41,18 +43,18 @@ $$
$\psi_2(x)$ can be found by replacing $x_1$ by $x_2$
2.
2.
$$
H = -\frac{mV_0^2}{\hbar^2}\begin{pmatrix}
1/2+\exp(-\frac{mV_0}{\hbar^2}(x_2-x_1)) &
1/2+\exp(-\frac{mV_0}{\hbar^2}(x_2-x_1)) &
\exp(\frac{mV_0}{\hbar^2}(x_2-x_1))\\
\exp(-\frac{mV_0}{\hbar^2}(x_2-x_1)) &
\exp(-\frac{mV_0}{\hbar^2}(x_2-x_1)) &
1/2+\exp(+\frac{mV_0}{\hbar^2}(x_2-x_1))
\end{pmatrix}
$$
3.
3.
$$
\epsilon_{\pm} = \beta(3/2+\cosh{2\alpha}+2\cosh{\alpha}\pm \cosh{\alpha})
......@@ -104,4 +106,3 @@ $$
$$
P = -\frac{2\gamma^2}{\mathcal{E}}(\frac{1}{\sqrt{\gamma^2+t^2}})
$$
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